SGS global teams of chemists and experts use a range of coal analytical calculations and indexes to arrive at the calorific values, total hydrogen, Coke Reactivity Index (CRI) and Coke Strength after Reaction (CSR) of your coal sample. Our third party test results and calculations provide you with reliable data that complies with international standards.

The following are some of the interesting protocols and calculations regularly used by SGS coal and coke specialists. These calculations are provided for your information, but SGS cannot guarantee that all data or formulas match the most current standards. Clients trading coal must familiarise themselves with the current standards being used in contracts.

**** Net CV calculation - refer to ASTM D5865-12 / ISO 1928-2009*** Moisture conversion to different bases - refer to ASTM D3180 / ISO 1170*

**Bases Conversion Factors:**Ref: ASTM D3180 / ISO 1170 - Conversion to different moisture bases**AD factor**(converts AD to Nominated Moisture (NM)):**(100-NM)/(100-ADM)**

NM = AD / ((100-NM)/(100-ADM))**Dry factor**(converts AD to Dry)**(100-ADM)/100**

Dry = AD / ((100-ADM)/100)**AR factor**(converts Dry to AR):**(100-TM)/100**

AR = Dry x ((100-TM))/100)**DAF factor**(converts Dry to DAF):**(100-Dry Ash)/100**

DAF = Dry / ((100-Dry Ash)/100)

**Two Stage Total Moisture Formula**(Refer to ASTM D3302 section 10)

Two stage total moisture determination is used when the coal sample is too small mass or too wet to divide or crush without the potential of losing significant amounts of moisture.

TMar, % = [Rm,ad, % x (100 – Fm,ad, %) / 100] + Fm,ad %

TM = Total moisture; Fm = Free Moisture; Rm = Residual moisture**Calorific Value Conversion Factors**Ref: ASTM 5865-12 X1.4. & ISO 1928-9 10.5

J/g = kcals/kg divided by 0.238846 OR multiplied 4.1868

J/g = Btu/lb multiplied by 2.326 OR divided by 0.429923

kcal/kg = J/g multiplied by 0.238846 OR divided by 4.1868

kcal/kg = Btu/lb divided by 1.8 or multiplied by 0.555556

Btu/lb = J/g divided 2.326 OR multiplied by 0.429923

Btu/lb = kcals/kg multiplied by 1.8 or divided by 0.555556**CO**(Directive 2003/87/EC) Directive 2007/589/EC_{2}Emission Factor

CO_{2}Emission Factor tCO_{2}/TJ =

= As Received Carbon x 3.667 x [10,000/NCV(p)] in kJ/kg

= As Received Carbon x 3.667 x [2388.46/NCV(p)] in kcal/kg**Standard Uncertainty of CO**(tCO2/TJ)_{2}Emission Factor

As part of new European Commission (EC) reporting requirements for CO_{2}emissions, the analyzing laboratory is asked to report “Standard Uncertainty of CO_{2}Emission Factor”, attributed to laboratory analysis, expressed as a standard deviation.

ISO reproducibility values for C(db) 1.00% and GCV(db) 300J/g, converted to as-received basis, are used in the calculation of Uncertainty.**Fuel Ratio**= Fixed Carbon / Volatile Matter**Ballast**= Ash(ar) + Total Moisture**Hydrogen in Coal**: Refer to ASTM 3180 / ISO 1170

In as much as hydrogen values may be reported on the basis of containing or not containing the hydrogen in water (moisture) associated with the sample, alternative conversion procedures are defined below.

Use the following conversions to report H including or excluding H in moisture:**Total Hydrogen as-determined (ad):**includes H in the analysis moisture- Hydrogen (
**excluding**H in moisture)

H(dry base) = [Total Hydrogen(ad)-(AMx0.1119)] x (100/(100-AM)) - Hydrogen (
**including**H in moisture)

H(ar) = [Total Hydrogen(db) x ((100-TM)/100)]+(0.1119*TM) - ISO 1170 reports H air-dried basis
**excluding**H in the as analyzed moisture.

H(air-dried) = Total Hydrogen(as-determined) - (Analysis Moisture x 0.1119)

Hydrogen and Oxygen Factors based on the atomic weight of H_{2}0

Hydrogen = Moisture X 0.1119

Oxygen = Moisture X 0.8881

- Hydrogen (
**DMMF Calculations**Dry Mineral Matter Free calculations (Reference ASTM D388)**Empirical Formula for estimation of Gross Calorific Value using Ultimate Analysis**(Ref: COAL Typology - Physics - Chemistry - Constitution; author D.W Krevelen; third edition 1993, page 528). All data is on a Dry Basis (DB) expressed as % weight.DULONG (1820) = (80.8 x C) + (344.6 x H) – (43.1 x O) + (25 x S) BOIE (1953) = (84 x C) + (277.7 x H) – (26.5 x O) + (15.0 x N) + (25 x S) SEYLER (1938) = (123.9 x C) + (388.1 x H) + (25 x O2) - 4269 NEAVEL (1986) = (81.05 x C) + (316.4 x H) – (29.9 x O) + (23.9 x S) - (3.5x Ash) MOTT & SPOONER (1940) OXYGEN < 15% = (80.3 x C) + (339 x H) - (34.7 x O) + (22.5 x S) GIVEN (1986) = (78.3 x C) + (339.1 x H) – (33.0 x O) + (22.1 x S) + 152 MOTT & SPOONER (1940) OXYGEN > 15% = (80.3 x C) + (339 x H) - (36.6 x O) + (0.17 x O2) + 22.5 x S

these formulas are not valid for coal blends. Refer to above Note for Seylers Formula.*NOTE:*Extract from COAL - D.W. Krevelen. (page 529) "All the empirical equations are modifications of the original Dulong equation with "some theoretical foundation", and are, by adaption to empirical CV data of coal, de facto empirical relationships. The correlations given by GIVEN (1986) and NEAVEL (1986) are the most reliable."

**Net Calorific Value (NCV) Calculations and Conversion Factors**Ref: Net Calorific Value (ASTM D5865-12)

The heat produced by combustion of a substance at a constant pressure of 0.1 Mpa (1 Atm), with any water formed remaining as vapour.**ASTM D5865-12 / D3180 at constant pressure**Qv-p= 0.01 * RT * (Had / (2*2.016)) - Oad / 31.9988 - Nad / 28.0134)

Qh = 0.01 * Hvap * (Had / 2.016)

Qmad = 0.01 * Hvap * (Mad / 18.0154)

Qmar = 0.01 *Hvap * (Mar / 18.0154)

Qvar = Qvad *((100-Mar) / (100-Mad))

Qpad(net) = Qvad(gross) + Qv-p - Qh – Qmad

Qpd(net) = (Qvad(gross) + Qv-p - Qh) * (100/(100-Mad)

Qpar(net) = ( Qvad(gross) + Qv-p - Qh) * (100 - Mar) / (100 - Mad) – Qmar**Where:**Qv-p = The energy associated with this change in the volume of the gaseous phase for the combustion reaction

R = the universal gas constant [8.3143 J/(mol *K)]

T = the standard thermochemical reference temperature (298.15 K)

Had = Had,m – 0.1119 * Mad (total Hydrogen – H in moisture)

Oad = Oad,m – 0.8881 * Mad (total Oxygen – O in moisture)

Hvap = heat of vaporization of water at constant pressure (43985 J/mol)

Qh = heat of vaporization of hydrogen content in the sample

Qmad = heat of vaporization of water content in the analysis sample

Qmar = heat of vaporization of total moisture content in the sample

Atomic Weights: O_{2}= 31.998 / N_{2}= 28.0134 / H_{2}2.016 / H_{2}O = 18.0154**ISO 1928-2009 at constant volume**Qv, net,m,J/g =( Q gr,v,d - 206.0 [ wHd ] ) x (1-0.01xM_{T}) - (23.05x M_{T})

Qv, net,m,kcal/kg = ( Q gr,v,d - 49.20 [ wHd ] ) x (1-0.01xM_{T}) - (5.51x M_{T})**ISO 1928-2009 at constant pressure**Qp, net,m,J/g =

{ Q gr,v,d - 212.2 [ wHd ] - 0.8 x [wOd + wNd] } x (1- 0.01M_{T}) - 24.43 x M_{T}

Qp, net,m,kcal/kg =

{ Q gr,v,d - 50.68 [ wHd ] - 0.191 x [wOd + wNd] } x (1- 0.01M_{T}) - 5.84 x M_{T}[ wHd ] = H content of the sample less Hydrogen present in the moisture

w(H)d = w(H) x 100/100-M_{T}

M_{T}= Total Moisture**Seyler’s Formula**Various parameters of coal can be estimated from the Ultimate Analysis and Calorific Value determinations, using Seyler's formula, and other similar calculations (e.g. Dulong's formula).**ISO 1928 2009 Determination of Gross Calorific Value**The ISO standard is the only international standard that allows for the estimation of hydrogen content to be calculated using Seyler’s Formula.

Seyler’s calculation is only valid for most bituminous coals.**Note 1.**NOT valid when the estimated Hdb is less than 3%**Note 2.**NOT valid when the Odaf content is greater than 15%**Note 3.**NOT valid for estimation of H if coal shipments are a blend of low rank coal, or anthracite, or petcoke, and bituminous coals**Note 4.**NOT valid for low rank coal, anthracite, petcoke, or coke

ISO 1928 2009 Part E.3.3

wH = 0.07 x w(V) + 0.000165 x qv,gr,m - 0.0285 x [ 100 - M_{T}- w(A) ]

w(H) - is the H content of sample less H contained in moisture, as % mass

w(V) - is the VM content of sample with moisture content M_{T}, as % mass

w(A) - is the ash content of sample with moisture content M_{T}, as % mass

qv,gr,m - is the gross CV of sample with moisture content M_{T}, in joules/g**MEAN SIZE OF COKE**(reference ISO 728 Annex A)

= (B(a-c)+C(b-d)+…+J(h-k) +100j)/200Where: a,b,c,d…h,j,k are the hole sizes, in mm., of successive sieves; 'A,B,C,D…H,J,K are the cumulative percentage oversizes for each of the sieves.

Note: The sieve with hole size 'a' is the smallest size through which all coke passes (i.e. A = 0%). The sieve with hole size "k" is the hypothetical sieve through which no coke will pass (k=0mm, K=100%).

**Where:**

TM is Total Moisture

ADM is Air Dried Moisture (Moisture in the Analysis Sample)

NM is Nominated Moisture

AR is As Received Basis

AD is As Determined (Air Dried) Basis

Dry is Dry Basis

DAF is Dry Ash Free Basis

### Coke Reactivity Index (CRI) and Coke Strength after Reaction (CSR)

When coke descends in the blast furnace, it is subjected to reaction with countercurrent CO_{2} and abrasion. These concurrent processes weaken the coke and chemically react with it to produce excess fines that can decrease the permeability of the blast furnace burden. SGS conducts CRI and CSR testing to provide high accuracy results with good turnaround times. CRI and CSR tests determine how much energy your coal will produce when being burned in the furnace.

The CRI/CSR test measures coke reactively in carbon dioxide at elevated temperatures and its strength after reaction by tumbling. In the test, duplicate 200g samples of ⅞” x ¾” (19 x 22 mm) sized coke are extracted from a minimum 1kg parent sample and reacted in a vessel with CO_{2} gas for two hours at 1100°C. The weight loss after the reaction equals the CRI. The reacted coke is then tumbled in an I-shaped tumbler for 600 revolutions at 20 rpm and is then weighed. The weight percent of the + ⅜” coke equals the CSR. Most blast furnaces will require a coke with a CSR greater than 60 and CRI less than 25.SGS is committed to providing accurate, cost effective blast furnace coke analysis for your operation.

SGS is the world leader in coal and coke analysis and testing. The data resulting from our analytical processes ensures optimal recovery rates and performance of your coal or coke.

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